Comprehensive Utilization of Dichloroethane

Created on 11.07

a) Brief Description of the Process

Brief Description of Dichloroethane Primary Distillation Process:

Purchased substandard dichloroethane or heavy components (containing approximately 75%~85% dichloroethane) are transported to the raw material oil tank farm for storage. They are then pumped into the still pot of the primary distillation tower via a raw material oil pump. The temperature is raised and controlled; under negative pressure, the primary distillation products within the temperature range of 45°C to 70°C are extracted as light components, and the primary distillation products within the temperature range of 70°C to 100°C are extracted as the finished dichloroethane product. The primary distillation system operates under negative pressure, and a water-ring vacuum pump is used to create a vacuum for the primary distillation system.

b) Pollution-Generating Links and Pollution Source Strength

Brief Description of Trichloropropane Primary Distillation Process:

Purchased epichlorohydrin high-boiler raw material oil (containing approximately 80%~90% trichloropropane) is transported to the raw material oil tank farm for storage. It is then pumped into the still pot of the primary distillation tower via a raw material oil pump. The temperature is raised and controlled; under negative pressure, the primary distillation products within the temperature range of 90°C to 105°C are extracted as light components, and the primary distillation products within the temperature range of 105°C to 170°C are extracted as the finished trichloropropane product. The primary distillation system operates under negative pressure, and a water-ring vacuum pump is used to create a vacuum for the primary distillation system.
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Process Flow and Pollution-Generating Nodes Diagram for Dichloroethane Recovery Production

A. The liquid from the top of the primary distillation tower is condensed and recovered through a condensation tower. During the recovery process, a small amount of non-condensable tail gas that cannot be condensed still contains residual dichloroethane gas. This gas is collected under negative pressure and, together with the vacuum pump tail gas, sent to an activated carbon adsorption device for adsorption treatment, then discharged through an exhaust stack.B. Through the previous heating process, the finished product receiving tank contains water-bearing steam. This part of the steam is separated by a steam-water separator. During the separation process, dichloroethane gas is generated. The volatile gas collected via the vacuum pump connection is sent to an activated carbon adsorption device for adsorption treatment, then discharged through an exhaust stack.C. The "large and small breathing" of solvent storage tanks (gas emissions caused by temperature/pressure changes and liquid level fluctuations) generates organic waste gas, which is discharged in an unorganized manner. The emission volume and pollutant concentration of this part of the waste gas are estimated uniformly.D. All heat supply for this project is provided by the industrial park's steam system.E. Still liquid is generated during the reaction process of the primary distillation tower.F. During the production process, equipment such as material transfer pumps and fans used for waste gas treatment will generate noise, with a sound source strength of approximately 65~95 dB(A).G. After primary distillation by the primary distillation unit, under negative pressure, the primary distillation products within the temperature range of 45°C to 70°C are extracted as light components. The light components mainly consist of allyl chloride, chloropropane, and water. After standing for stratification, the generated wastewater is sent to the wastewater treatment station for treatment, and the separated substances are sold externally as auxiliary materials.H. Condensed water is generated during the condensation process. This condensed water is recycled for reuse and not discharged externally.

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